Browsing by Subject "Kinetics"
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Interconversion of conjugated and nonconjugated polyolefin cobalt complexes in two oxidation states: an electrochemical and NMR study
(The American Chemical Society: Journal of the American Chemical Society, 1986-11-26)The kinetics of interconversion between the conjugated (1,3) and nonconjugated (1,5) isomers of cyclooctatetraene (cot) complexes of CpCo [Cp = C5H5] 1 and *CpCo [*Cp = C5Me5] 2 have been studied. Dynamic NMR studies were ... -
Origins of high sequence selectivity: a stopped-flow kinetics study of DNA/RNA hybridization by duplex- and triplex-forming oligonucleotides
(The American Chemical Society: Biochemistry, 1995-08-01)Stopped-flow UV kinetics and thermal denaturation experiments are used to examine the origins of high sequence selectivity and binding affinity of circular triplex-forming oligonucleotides with single-stranded DNA/RNA ... -
Solvent effects on the kinetics of simple electrochemical reactions. Further examination of metal ethylenediamine and ammine redox couples.
(Elsevier: Journal of Electroanalytical Chemistry, 1985-09-10)The dependence of the kinetics of Co(en)33+/2+ exchange (en=ethylenediamine) at mercury electrodes upon the nature of the solvent is discussed further by examining the preexponential factors, Acorr, as well as double-layer ...