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Pressure effects on the photophysical properties of the platinum(II) dimer Pt2(POP)44- (POP = .mu.-.eta.2-H2P2O52-) and related d8-d8 dinuclear complexes in solution
(The American Chemical Society: Journal of Physical Chemistry, 1988-06-30)
The effect of hydrostatic pressure (0.1-300 MPa) upon phosphorescence lifetimes in fluid solution has been examined for four dinuclear d8-d8 transition-metal complexes: A, Pt2(POP)44- (POP = u-n2-H2P2O52-); B, Rh2(br)42+ ...
Photoreactions of docosylcarbonyloctairidate(2-). Homolytic cleavage of an unsupported metal-metal bond linking two tetrahedral iridium carbonyl clusters
(The American Chemical Society: Inorganic Chemistry, 1988-02-28)
Photoisomerization of the ruthenium cluster HRu3(CO)10(.mu.-COCH3), an unprecedented oxygen-to-carbon alkyl migration
(The American Chemical Society: Journal of the American Chemical Society, 1986-11-26)
Photoreactions of the triruthenium cluster Ru3(CO)12 and substituted analogs
(The American Chemical Society: Journal of the American Chemical Society, 1986-04-16)
Reported is a comprehensive investigation of the medium, ligand, and wavelength effects on the quantum yields and flash photolysis kinetics for the photofragmentation and photosubstitution reactions of the trinuclear ...
Evaluation of two viral inactivation methods for the preparation of safer factor VIII and factor IX concentrates
(Blackwell Publishing: Transfusion, 1985-11)
We report here the results of our evaluation of two procedures to eliminate viruses in factor VIII and factor IX coagulation factor concentrates. Both procedures were equally effective in the in vitro destruction of marker ...
Palladium/hydrogen catalyzed alcoholysis of benzylsilanes
(Elsevier: Journal of Organometallic Chemistry, 1976)
Certain benzylsilanes are converted to methoxy or ethoxysilanes and toluene when treated with methanol or ethanol in the presence of hydrogen and catalytic amounts of palladium on charcoal. The reaction is promoted by a ...
The total synthesis and anti-fertility activity of 6-silasteroids
(Elsevier: Tetrahedron, 1975)
4,4-Dimethyl-6-methoxy-4-sila-1-tetralone (2) was prepared by a modified literature procedure and converted to 3-methoxy-6,6-dimethyl-6-silaestra-1,3,5(10),8,14-pentaen-17β-yl acetate (5c). Catalytic hydrogenation of 5c ...
Apparent cytochrome gene dose effects in F-lac and F-gal heterogenotes of Escherichia coli.
(Elsevier: Archives of Biochemistry and Biophysics, 1972-06)
The levels of b- and c-type cytochromes and cytochromes a1 and a2 are elevated in a partial diploid strain of E. coli carrying the F2-gal episome under a variety of different growth conditions. Only the levels of b- and ...