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Stepwise mechanism for oxidative addition of iodine to organotellurium(II) compounds as observed by stopped-flow spectroscopy
(The American Chemical Society: Organometallics, 1995-03)
The reaction of iodine with a series of diorgano tellurides was monitored by stopped-flow spectroscopy. For dihexyl telluride (11, diphenyl telluride (2), di-p-anisyl telluride (31, and phenyl 2-((dimethylamino)methyl)phenyl ...
Stepwise mechanism for oxidative addition of bromine to organoselenium(II) and organotellurium(II) compounds
(The American Chemical Society: Organometallics, 1994-08)
The oxidative-addition reactions of bromine (5 x 10(-4) or 5 x 10(-5) M) to phenyl selenide (1), phenyl telluride (2), 2,6-di-tert-butylselenopyran-4-one (3), 2,6-di-tert-butyltelluropyran-4-one (4), 2,6-diphenyltelluropyran-4-one ...