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Photoisomerization of the ruthenium cluster HRu3(CO)10(.mu.-COCH3), an unprecedented oxygen-to-carbon alkyl migration
(The American Chemical Society: Journal of the American Chemical Society, 1986-11-26)
Interconversion of conjugated and nonconjugated polyolefin cobalt complexes in two oxidation states: an electrochemical and NMR study
(The American Chemical Society: Journal of the American Chemical Society, 1986-11-26)
The kinetics of interconversion between the conjugated (1,3) and nonconjugated (1,5) isomers of cyclooctatetraene (cot) complexes of CpCo [Cp = C5H5] 1 and *CpCo [*Cp = C5Me5] 2 have been studied. Dynamic NMR studies were ...
Study of interfacial curvature in a three-component microemulsion with equal volumes of water and oil
(American Physical Society, 1986-11-17)
We have used a double-contrast-variation method in small-angle neutron scattering to study the structure of a single-phase microemulsion containing equal amounts of oil (decane) and water stabilized with an aerosol OT ...
Cation binding at the air-water interface by macromolecules bearing pendant crown ethers moieties
(American Chemical Society: Journal of the American Chemical Society, 1986-09-17)
In solution, the ion-binding characteristics of crown ethers and macromolecules containing macrocyclic ether moieties have been studied extensively. These ionophores are finding application in membranes, thin film sensors, ...
Millimeter wave radiation from a rotating electron ring subjected to an azimuthally periodic wiggler magnetic field
(Elsevier B.V. - Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, 1986-09)
The generation of millimeter wave radiation (80–180 GHz) caused by the interaction of a rotating electron ring (2 MV, 1.4–3.6 kA, 5 ns) with an azimuthally periodic wiggler magnetic field has been studied experimentally ...
Correction of thermal imagery for atmospheric effects using aircraft measurement and atmospheric modeling techniques
(Optical Society of America (OSA), 1986-08)
Airborne measurements of atmospheric-path transmission and atmospheric-path (upwelled) radiance in the
8-14-gm band were obtained by applying a multiple altitude and a dual-view angle calibration technique to
thermal IR ...
Radicals of C7-polyolefin cobalt complexes: electrochemistry, reaction routes, and structure of a resulting dimer
(The American Chemical Society: Organometallics, 1986-07)
The reduction and oxidation of several cyclopentadienyl (Cp) cobalt complexes with pi-bonded CTpolyolefin ligands have been studied by electrochemical methods. The cycloheptadienyl complex CpCo(n^5-C7H9)+ is reversibly ...
Rotational spectroscopy of DO2 by FIR LMR and millimeter-wave absorption
(Elsevier: Journal of Molecular Spectroscopy, 1986-07)
We report the measurement of approximately 50 rotational transitions in the DO2 radical between 230 and 2530 GHz by high-resolution millimeter-wave and far-infrared laser magnetic resonance spectroscopy. The radical was ...
Phosphorus-31 NMR spectroscopy using a loop-gap resonator
(Elsevier: Journal of Magnetic Resonance, 1986-06-15)
The loop-gap resonator provides a simple and convenient alternative for large volume probes that are now practical for applications to NMR spectroscopy. A 400 ml probe is described for use in a large-bore magnet which is ...
Photoreactions of the triruthenium cluster Ru3(CO)12 and substituted analogs
(The American Chemical Society: Journal of the American Chemical Society, 1986-04-16)
Reported is a comprehensive investigation of the medium, ligand, and wavelength effects on the quantum yields and flash photolysis kinetics for the photofragmentation and photosubstitution reactions of the trinuclear ...