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Photoreactions of the triruthenium cluster HRu3(CO)10 (.mu.-COCH3). Isomerization of the bridging alkylidyne ligand and competing ligand substitutions
(The American Chemical Society: Journal of the American Chemical Society, 1989-01-18)
Irradiation of the title compound HRu3(CO)10(u-COCH3) (A) in hydrocarbon solution under CO leads to the formation of the bridging u,n2 acyl isomer HRu3(CO)10(u,n2-C(O)CH3) (B). Quantum yields for isomerization phi-i were ...
Pressure effects on the photophysical properties of the platinum(II) dimer Pt2(POP)44- (POP = .mu.-.eta.2-H2P2O52-) and related d8-d8 dinuclear complexes in solution
(The American Chemical Society: Journal of Physical Chemistry, 1988-06-30)
The effect of hydrostatic pressure (0.1-300 MPa) upon phosphorescence lifetimes in fluid solution has been examined for four dinuclear d8-d8 transition-metal complexes: A, Pt2(POP)44- (POP = u-n2-H2P2O52-); B, Rh2(br)42+ ...
Photoreactions of docosylcarbonyloctairidate(2-). Homolytic cleavage of an unsupported metal-metal bond linking two tetrahedral iridium carbonyl clusters
(The American Chemical Society: Inorganic Chemistry, 1988-02-28)
Photoisomerization of the ruthenium cluster HRu3(CO)10(.mu.-COCH3), an unprecedented oxygen-to-carbon alkyl migration
(The American Chemical Society: Journal of the American Chemical Society, 1986-11-26)
Photoreactions of the triruthenium cluster Ru3(CO)12 and substituted analogs
(The American Chemical Society: Journal of the American Chemical Society, 1986-04-16)
Reported is a comprehensive investigation of the medium, ligand, and wavelength effects on the quantum yields and flash photolysis kinetics for the photofragmentation and photosubstitution reactions of the trinuclear ...