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Photoreactions of the triruthenium cluster HRu3(CO)10 (.mu.-COCH3). Isomerization of the bridging alkylidyne ligand and competing ligand substitutions
(The American Chemical Society: Journal of the American Chemical Society, 1989-01-18)
Irradiation of the title compound HRu3(CO)10(u-COCH3) (A) in hydrocarbon solution under CO leads to the formation of the bridging u,n2 acyl isomer HRu3(CO)10(u,n2-C(O)CH3) (B). Quantum yields for isomerization phi-i were ...