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Fast charge-transfer reactions of binuclear complexes undergoing large changes in metal---metal bond lengths
(Elsevier: Journal of Electroanalytical Chemistry, 1987-05-08)
Heterogeneous electron-transfer rates have been measured for three binuclear complexes, Cp2Fe2(CO)2(μ-SMe)2, 1, Cp2Fe2(CO)2(μ-PPh2)2, 2, and Cp2Mo2(μ-SMe)4, 3. Dahl and co-workers had shown previously that the cations of ...
Heterogeneous electron-transfer kinetics for some multiply bonded dirhenium complexes
(Elsevier: Journal of Electroanalytical Chemistry, 1985-12-10)
Standard electrochemical rate constants kexob have been measured for the two sequential one-electron oxidations of triply-bonded dirhenium(II) complexes Re2X4(PR3)4, where X = Cl or Br, and PR3 = a monodentate tertiary ...