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Solvent effects on the kinetics of simple electrochemical reactions. Further examination of metal ethylenediamine and ammine redox couples.
(Elsevier: Journal of Electroanalytical Chemistry, 1985-09-10)
The dependence of the kinetics of Co(en)33+/2+ exchange (en=ethylenediamine) at mercury electrodes upon the nature of the solvent is discussed further by examining the preexponential factors, Acorr, as well as double-layer ...
Role of solvent reorganization dynamics in electron-transfer processes. Theory-experiment comparisons for electrochemical and homogeneous electron exchange involving metallocene redox couples
(The American Chemical Society: Journal of Physical Chemistry, 1985-06-20)
Electrochemical rate constants and activation parameters are reported for the electron exchange of five metallocene couples and bis(benzene)chromium(I/0) in eight solvents at mercury electrodes. The solvents (acetonitrile, ...
Influence of solvent reorientation dynamics upon the kinetics of some electron-exchange reactions
(Elsevier: Chemical Physics Letters, 1985-01-11)
The role of solvent reorientation dynamics is explored for outer-sphere electron transfer by examining the solvent-dependent rates for electrochemical exchange of selected organometallic redox couples. The observations are ...