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Stereochemistry and mechanisms of cyclopropane ring cleavage. Addition of hydrogen chloride to tetracyclo[3.2.0.02,7.04,6]heptane-1,5-dicarboxylic acid (quadricyclenedicarboxylic acid)
(The American Chemical Society: The Journal of Organic Chemistry, 1971-09-24)
Addition of hydrogen chloride to tetracyc10[3.2.0.0^2,7.0^4,6] heptane-l15-dicarboxylic acid (1, quadricyclenedicarboxylic acid) under various conditions results in two products, exo-5-chlorotricyclo[2.2,1.0^2,6] ...
Stereochemistry and mechanisms of the addition of deuterium chloride to bicyclo[2.2.1]heptadiene (norbornadiene) and to tetracyclo[3.2.02,7.04,6]heptane (quadricyclene)
(The American Chemical Society: The Journal of Organic Chemistry, 1971-09-24)
Addition of hydrogen chloride and deuterium chloride to bicyclo [2.2.1] heptadiene (I, norbornadiene) results in (unlabeled and labeled, respectively) exo-dehydronorbornyl chloride (III) and nortricyclyl chloride (IV). The ...