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Electrochemical oxidation and reduction of methylene-bridged complexes of manganese, cobalt, and rhodium
(The American Chemical Society: Organometallics, 1987-08)
The oxidation and reduction of a series of alkylidene-bridged dimetallic compounds containing Mn, Co, or Rh have been studied by electrochemical and spectroscopic techniques. Oxidation results in production of a cation ...
Fast charge-transfer reactions of binuclear complexes undergoing large changes in metal---metal bond lengths
(Elsevier: Journal of Electroanalytical Chemistry, 1987-05-08)
Heterogeneous electron-transfer rates have been measured for three binuclear complexes, Cp2Fe2(CO)2(μ-SMe)2, 1, Cp2Fe2(CO)2(μ-PPh2)2, 2, and Cp2Mo2(μ-SMe)4, 3. Dahl and co-workers had shown previously that the cations of ...
Interconversion of conjugated and nonconjugated polyolefin cobalt complexes in two oxidation states: an electrochemical and NMR study
(The American Chemical Society: Journal of the American Chemical Society, 1986-11-26)
The kinetics of interconversion between the conjugated (1,3) and nonconjugated (1,5) isomers of cyclooctatetraene (cot) complexes of CpCo [Cp = C5H5] 1 and *CpCo [*Cp = C5Me5] 2 have been studied. Dynamic NMR studies were ...
Radicals of C7-polyolefin cobalt complexes: electrochemistry, reaction routes, and structure of a resulting dimer
(The American Chemical Society: Organometallics, 1986-07)
The reduction and oxidation of several cyclopentadienyl (Cp) cobalt complexes with pi-bonded CTpolyolefin ligands have been studied by electrochemical methods. The cycloheptadienyl complex CpCo(n^5-C7H9)+ is reversibly ...