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Electrochemical oxidation and reduction of methylene-bridged complexes of manganese, cobalt, and rhodium
(The American Chemical Society: Organometallics, 1987-08)
The oxidation and reduction of a series of alkylidene-bridged dimetallic compounds containing Mn, Co, or Rh have been studied by electrochemical and spectroscopic techniques. Oxidation results in production of a cation ...
Unusual oxidative behavior of (.eta.5-C5R5)M(CO)2 (R = H, CH3; M = Rh, Co) complexes at mercury and platinum electrodes
(The American Chemical Society: Inorganic Chemistry, 1987-06-17)
The electrochemical oxidative behavior of a series of cyclopentadienyl and pentamethylcyclopentadienyl carbonyl complexes of rhodium and cobalt is described. The voltammetric, polarographic, and coulometric data from the ...
Fast charge-transfer reactions of binuclear complexes undergoing large changes in metal---metal bond lengths
(Elsevier: Journal of Electroanalytical Chemistry, 1987-05-08)
Heterogeneous electron-transfer rates have been measured for three binuclear complexes, Cp2Fe2(CO)2(μ-SMe)2, 1, Cp2Fe2(CO)2(μ-PPh2)2, 2, and Cp2Mo2(μ-SMe)4, 3. Dahl and co-workers had shown previously that the cations of ...