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Role of solvent reorganization dynamics in electron-transfer processes. Theory-experiment comparisons for electrochemical and homogeneous electron exchange involving metallocene redox couples
(The American Chemical Society: Journal of Physical Chemistry, 1985-06-20)
Electrochemical rate constants and activation parameters are reported for the electron exchange of five metallocene couples and bis(benzene)chromium(I/0) in eight solvents at mercury electrodes. The solvents (acetonitrile, ...
Influence of solvent reorientation dynamics upon the kinetics of some electron-exchange reactions
(Elsevier: Chemical Physics Letters, 1985-01-11)
The role of solvent reorientation dynamics is explored for outer-sphere electron transfer by examining the solvent-dependent rates for electrochemical exchange of selected organometallic redox couples. The observations are ...