Browsing Citations Only by Author "D'Souza, Christopher"
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Efficient hydride-assisted isomerization of alkenes via rhodium catalysis
Morrill, Terence; D'Souza, Christopher (The American Chemical Society: Organometallics, 2003-04-14)We find that alkenes isomerize rapidly in the presence of catalytic amounts of a hydroborating reagent and a rhodium compound. The hydroborating reagent is apparently responsible for the in situ generation of a metal hydride ... -
Transition-metal-promoted hydroboration of alkenes: a unique reversal of regioselectivity
Morrill, Terence; D'Souza, Christopher; Yang, Lu; Sampognaro, Anthony (The American Chemical Society: The Journal of Organic Chemistry, 2002-04-19)When hydroboration of 1-octene is carried out in the presence of catalytic amounts of rhodium trichloride followed by the usual oxidation (hydrogen peroxide in aqueous alkali), only minor proportions of 1-octanol (2.4%) ...