Browsing Citations Only by Author "Geiger, William"
Now showing items 1-5 of 5
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Cp3M3(CO)3 clusters: electrocatalytic isomerization and effect of changes in metal and carbon monoxide bonding mode on electron-transfer properties
Mevs, Judith; Gennett, Thomas; Geiger, William (The American Chemical Society: Organometallics, 1991-05)The electrochemical reduction of three trinuclear complexes of general formula Cp3M3(CO)3 (Cp = n^5-cyclopentadienyl, M = Co or Rh) was studied in nonaqueous solutions. The cobalt complex Cp3CO3(CO)3 (3) is reduced by one ... -
Electrochemical oxidation and reduction of methylene-bridged complexes of manganese, cobalt, and rhodium
Geiger, William; Gennett, Thomas; McVicar, William (The American Chemical Society: Organometallics, 1987-08)The oxidation and reduction of a series of alkylidene-bridged dimetallic compounds containing Mn, Co, or Rh have been studied by electrochemical and spectroscopic techniques. Oxidation results in production of a cation ... -
Fast charge-transfer reactions of binuclear complexes undergoing large changes in metal---metal bond lengths
Gennett, Thomas; Geiger, William; Willet, Brian; Anson, Fred (Elsevier: Journal of Electroanalytical Chemistry, 1987-05-08)Heterogeneous electron-transfer rates have been measured for three binuclear complexes, Cp2Fe2(CO)2(μ-SMe)2, 1, Cp2Fe2(CO)2(μ-PPh2)2, 2, and Cp2Mo2(μ-SMe)4, 3. Dahl and co-workers had shown previously that the cations of ... -
Interconversion of conjugated and nonconjugated polyolefin cobalt complexes in two oxidation states: an electrochemical and NMR study
Geiger, William; Gennett, Thomas; Grzeszczuk, Maria; Lane, Gregg; Moraczewski, Jerome; Salzer, Albrecht; Smith, Donald (The American Chemical Society: Journal of the American Chemical Society, 1986-11-26)The kinetics of interconversion between the conjugated (1,3) and nonconjugated (1,5) isomers of cyclooctatetraene (cot) complexes of CpCo [Cp = C5H5] 1 and *CpCo [*Cp = C5Me5] 2 have been studied. Dynamic NMR studies were ... -
Radicals of C7-polyolefin cobalt complexes: electrochemistry, reaction routes, and structure of a resulting dimer
Geiger, William; Gennett, Thomas; Lane, Gregg (The American Chemical Society: Organometallics, 1986-07)The reduction and oxidation of several cyclopentadienyl (Cp) cobalt complexes with pi-bonded CTpolyolefin ligands have been studied by electrochemical methods. The cycloheptadienyl complex CpCo(n^5-C7H9)+ is reversibly ...