The Mass spectral analyses of deuterated and undeuterated bridged polycyclic acetates
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The mass spectral analyses of exo-dehydronorbornyl (Ia) and nortricyclyl (IIa) acetates are reported. In addition, the mass spectra are reported for exo-cis-3-deuteriodehydro-2-norbornyl acetate (IIIa) and for a sample containing equal amounts of C3-deuterio- and C7-deuterio-exo-dehydro-2-norbornyl acetate (IIIa and IVa). These spectra have been used to develop a technique to scrutinize those cations which determine the location of deuterium in dehydronorbornyl ring skeletons.