A soluble linear Schiff-base coordination polymer containing eight-coordinate zirconium (IV)
| dc.contributor.author | Archer, Ronald | en_US |
| dc.contributor.author | Illingsworth, Marvin | en_US |
| dc.contributor.author | Rau, Denise | en_US |
| dc.contributor.author | Hardiman, Christopher | en_US |
| dc.date.accessioned | 2006-07-19T19:39:56Z | en_US |
| dc.date.available | 2006-07-19T19:39:56Z | en_US |
| dc.date.issued | 1985-07 | en_US |
| dc.identifier.citation | Macromolecules 18N7 (1985) 1371-1376 | en_US |
| dc.identifier.issn | 1520-5835 | en_US |
| dc.identifier.uri | http://hdl.handle.net/1850/2169 | en_US |
| dc.description.abstract | The first soluble linear Schiff-base heavy-metal coordination polymer has been synthesized via the condensation of 1,2,4,5-tetraaminobenzene and tetrakis(salicylaldehydato)zirconium(IV) in dry dimethyl sulfoxide. The (N, N',N”,N”’-tetrasalicylidene-1,2,4,5-tetraaminobenzenato)zirconium(IV) polymer has a number-average molecular weight of up to 4.9 X 10^4 based on inherent viscosity, gel permeation chromatography, and elemental analysis. Spectral properties of this polymer indicate a structure analogous to the model compound bis(N,N’-disalicylidene-l,2-phenylenediamino)zirconium(IV). Thermal characterization of the polymer is also discussed. | en_US |
| dc.format.extent | 31371 bytes | en_US |
| dc.format.mimetype | application/pdf | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | The American Chemical Society: Macromolecules | en_US |
| dc.subject | Chelation | en_US |
| dc.subject | Polymers | en_US |
| dc.subject | Synthesis | en_US |
| dc.subject | Zirconium | en_US |
| dc.title | A soluble linear Schiff-base coordination polymer containing eight-coordinate zirconium (IV) | en_US |
| dc.type | Abstract | en_US |
| dc.identifier.url | http://dx.doi.org/10.1021/ma00149a003 |
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