Reactions of hydroxyl radicals with some hydrogen halides
| dc.contributor.author | Takacs, Gerald | en_US |
| dc.contributor.author | Glass, G. | en_US |
| dc.date.accessioned | 2006-07-19T19:58:25Z | en_US |
| dc.date.available | 2006-07-19T19:58:25Z | en_US |
| dc.date.issued | 1973-08-02 | en_US |
| dc.identifier.citation | The Journal of Physical Chemistry 77N16 (1973) 1948-1951 | en_US |
| dc.identifier.issn | 1520-5215 | en_US |
| dc.identifier.uri | http://hdl.handle.net/1850/2227 | en_US |
| dc.description.abstract | The reactions of OH with HCl and HI have been studied in a fast flow system. Hydroxyl radicals were generated by NO2 titration of atomic hydrogen, and concentrations of OH, Cl , and I were determined at various reaction times from their epr spectra. At 295 K, rate constants obtained for reactions 1 and 2 were (6.4 +- 1.5) X 10^-13 and (1.3 +- 0.5) x 10^-11 cm3 molecule-1 sec-1, respectively: OH + HCl -> H2O + CI (1); and OH + HI -> H2O +I (2). Using these values, and others obtained from the literature, a comparison was made of the rate constants and activation energies of the reactions of OH with HCl, HBr and HI. | en_US |
| dc.format.extent | 31371 bytes | en_US |
| dc.format.mimetype | application/pdf | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | The American Chemical Society: The Journal of Physical Chemistry | en_US |
| dc.title | Reactions of hydroxyl radicals with some hydrogen halides | en_US |
| dc.type | Abstract | en_US |
| dc.subject.keyword | Hydrogen halides | en_US |
| dc.subject.keyword | Hydroxyl radicals | en_US |
| dc.subject.keyword | Reaction rate | en_US |
| dc.identifier.url | http://dx.doi.org/10.1021/j100635a005 |
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