| dc.contributor.author | Takacs, Gerald | en_US |
| dc.contributor.author | Glass, G. | en_US |
| dc.date.accessioned | 2006-07-19T19:58:40Z | en_US |
| dc.date.available | 2006-07-19T19:58:40Z | en_US |
| dc.date.issued | 1973-04-12 | en_US |
| dc.identifier.citation | The Journal of Physical Chemistry 77N8 (1973) 1060-1064 | en_US |
| dc.identifier.issn | 1520-5215 | en_US |
| dc.identifier.uri | http://hdl.handle.net/1850/2228 | en_US |
| dc.description.abstract | A fast discharge-flow system was used to study reactions of hydrogen atoms and hydroxyl radicals with hydrogen bromide at 295 K. The reactions were followed by monitoring the epr spectra of H(2S1/2), Br(2P3/2), and OH(2pi3/2) at a number of different reaction times. A fluorinated halocarbon coating, applied to the flow tube, was found to be extremely effective in eliminating wall recombination of Br(2P3/2). Rate constants of (3.4 +- 0.8) x 10^-12 and (5.1 +- 1.0) x 10^-12 cm3 molecule-1 sec-1 were obtained for the reactions H + HBr -> H2 + Br and OH + HBr -> H20 + Br, respectively. An unsuccessful search was made for Br(2P1/2). | en_US |
| dc.format.extent | 31371 bytes | en_US |
| dc.format.mimetype | application/pdf | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | The American Chemical Society: The Journal of Physical Chemistry | en_US |
| dc.title | Reactions of hydrogen atoms and hydroxyl radicals with hydrogen bromide | en_US |
| dc.type | Abstract | en_US |
| dc.subject.keyword | Hydrogen bromide | en_US |
| dc.subject.keyword | Hydroxyl radicals | en_US |
| dc.subject.keyword | Reaction rate | en_US |
| dc.identifier.url | http://dx.doi.org/10.1021/j100627a019 | |
