Browsing by Author "Cristol, Stanley"

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    • Addition of acetic acid to norbornadiene. Mechanisms of addition reactions 

      Cristol, Stanley; Morrill, Terence; Sanchez, Robert (The American Chemical Society: The Journal of Organic Chemistry, 1966-09-12)
      The addition of acetic acid to norbornadiene (I) has been studied under a large variety of conditions and the extents of both homoconjugate addition and Wagner-Meerwein rearrangements accompanying addition have been ...

    • The Catalyzed addition of acetic acid to norbornadiene 

      Cristol, Stanley; Morrill, Terence; Sanchez, Robert (The American Chemical Society: The Journal of Organic Chemistry, 1966-09-12)
      An investigation of the acid-catalyzed addition of acetic acid to norbornadiene (I)to form ezo-dehydronorbornyl acetate (II) and nortricyclyl acetate (III) has been carried out. Catalysis by sodium perchlorate was similar ...

    • The Mass spectral analyses of deuterated and undeuterated bridged polycyclic acetates 

      Cristol, Stanley; Sanchez, Robert; Morrill, Terence (The American Chemical Society: The Journal of Organic Chemistry, 1966-09-12)
      The mass spectral analyses of exo-dehydronorbornyl (Ia) and nortricyclyl (IIa) acetates are reported. In addition, the mass spectra are reported for exo-cis-3-deuteriodehydro-2-norbornyl acetate (IIIa) and for a sample ...

    • Rearrangements in the acetolysis of exo-dehydro-2-norbornyl p-bromobenzenesulfonate 

      Cristol, Stanley; Morrill, Terence; Sanchez, Robert (American Chemical Society: Journal of the American Chemical Society, 1966-07-05)
      exo-3-Deuteriodehydro-2-norbornyl p-bromobenzenesulfonate (VIIb) solvolyzes in glacial acetic acid to give about 7 % of an equimolar mixture of exo-3-deuteriodehydro-2-norbornyl acetate (VIId) and 7-deuteriodehydro-2-norbornyl ...

    • Stereochemistry and mechanisms of cyclopropane ring cleavage. Addition of hydrogen chloride to tetracyclo[3.2.0.02,7.04,6]heptane-1,5-dicarboxylic acid (quadricyclenedicarboxylic acid) 

      Cristol, Stanley; Harrington, J. Kenneth; Morrill, Terence; Greenwald, Brian (The American Chemical Society: The Journal of Organic Chemistry, 1971-09-24)
      Addition of hydrogen chloride to tetracyc10[3.2.0.0^2,7.0^4,6] heptane-l15-dicarboxylic acid (1, quadricyclenedicarboxylic acid) under various conditions results in two products, exo-5-chlorotricyclo[2.2,1.0^2,6] ...

    • The Uncatalyzed addition of acetic acid to norbornadiene 

      Cristol, Stanley; Morrill, Terence; Sanchez, Robert (The American Chemical Society: The Journal of Organic Chemistry, 1966-09-12)
      The uncatalyzed addition of acetic acid to norbornadiene (I) to give mixtures of ezo-dehydronorbornyl acetate (II) and nortricyclyl acetate (III) was studied. Rates of addition and ratios of II/III (degree of homoallylic ...