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The Uncatalyzed addition of acetic acid to norbornadiene
(The American Chemical Society: The Journal of Organic Chemistry, 1966-09-12)
The uncatalyzed addition of acetic acid to norbornadiene (I) to give mixtures of ezo-dehydronorbornyl acetate (II) and nortricyclyl acetate (III) was studied. Rates of addition and ratios of II/III (degree of homoallylic ...
Rearrangements in the acetolysis of exo-dehydro-2-norbornyl p-bromobenzenesulfonate
(American Chemical Society: Journal of the American Chemical Society, 1966-07-05)
exo-3-Deuteriodehydro-2-norbornyl p-bromobenzenesulfonate (VIIb) solvolyzes in glacial acetic acid to give about 7 % of an equimolar mixture of exo-3-deuteriodehydro-2-norbornyl acetate (VIId) and 7-deuteriodehydro-2-norbornyl ...