Browsing Meeting minutes, announcements and publications from RIT Colleges by Author "Sanchez, Robert"

Now showing items 1-5 of 5

    • Addition of acetic acid to norbornadiene. Mechanisms of addition reactions 

      Cristol, Stanley; Morrill, Terence; Sanchez, Robert (The American Chemical Society: The Journal of Organic Chemistry, 1966-09-12)
      The addition of acetic acid to norbornadiene (I) has been studied under a large variety of conditions and the extents of both homoconjugate addition and Wagner-Meerwein rearrangements accompanying addition have been ...

    • The Catalyzed addition of acetic acid to norbornadiene 

      Cristol, Stanley; Morrill, Terence; Sanchez, Robert (The American Chemical Society: The Journal of Organic Chemistry, 1966-09-12)
      An investigation of the acid-catalyzed addition of acetic acid to norbornadiene (I)to form ezo-dehydronorbornyl acetate (II) and nortricyclyl acetate (III) has been carried out. Catalysis by sodium perchlorate was similar ...

    • The Mass spectral analyses of deuterated and undeuterated bridged polycyclic acetates 

      Cristol, Stanley; Sanchez, Robert; Morrill, Terence (The American Chemical Society: The Journal of Organic Chemistry, 1966-09-12)
      The mass spectral analyses of exo-dehydronorbornyl (Ia) and nortricyclyl (IIa) acetates are reported. In addition, the mass spectra are reported for exo-cis-3-deuteriodehydro-2-norbornyl acetate (IIIa) and for a sample ...

    • Rearrangements in the acetolysis of exo-dehydro-2-norbornyl p-bromobenzenesulfonate 

      Cristol, Stanley; Morrill, Terence; Sanchez, Robert (American Chemical Society: Journal of the American Chemical Society, 1966-07-05)
      exo-3-Deuteriodehydro-2-norbornyl p-bromobenzenesulfonate (VIIb) solvolyzes in glacial acetic acid to give about 7 % of an equimolar mixture of exo-3-deuteriodehydro-2-norbornyl acetate (VIId) and 7-deuteriodehydro-2-norbornyl ...

    • The Uncatalyzed addition of acetic acid to norbornadiene 

      Cristol, Stanley; Morrill, Terence; Sanchez, Robert (The American Chemical Society: The Journal of Organic Chemistry, 1966-09-12)
      The uncatalyzed addition of acetic acid to norbornadiene (I) to give mixtures of ezo-dehydronorbornyl acetate (II) and nortricyclyl acetate (III) was studied. Rates of addition and ratios of II/III (degree of homoallylic ...