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Now showing items 11-20 of 26
A simple and complete purification of single-walled carbon nanotube materials
(Wiley: Advanced Materials, 1999-11)
Use of poly(ester-sulfonic acid) film-coated electrodes as amperometric detectors in flow injection analysis
(Elsevier: Talanta, 1995-12)
Within the past several years significant advances have been made towards the development and incorporation of chemically modified electrodes as selective detectors for high performance liquid chromatography and flow ...
Cp3M3(CO)3 clusters: electrocatalytic isomerization and effect of changes in metal and carbon monoxide bonding mode on electron-transfer properties
(The American Chemical Society: Organometallics, 1991-05)
The electrochemical reduction of three trinuclear complexes of general formula Cp3M3(CO)3 (Cp = n^5-cyclopentadienyl, M = Co or Rh) was studied in nonaqueous solutions. The cobalt complex Cp3CO3(CO)3 (3) is reduced by one ...
Voltammetric determination of the ion-exchange behavior of poly(ester sulfonic acid) anionomers in acentonitrille
(The American Chemical Society: Analytical Chemistry, 1990-10-01)
Electrochemical oxidation and reduction of methylene-bridged complexes of manganese, cobalt, and rhodium
(The American Chemical Society: Organometallics, 1987-08)
The oxidation and reduction of a series of alkylidene-bridged dimetallic compounds containing Mn, Co, or Rh have been studied by electrochemical and spectroscopic techniques. Oxidation results in production of a cation ...
Unusual oxidative behavior of (.eta.5-C5R5)M(CO)2 (R = H, CH3; M = Rh, Co) complexes at mercury and platinum electrodes
(The American Chemical Society: Inorganic Chemistry, 1987-06-17)
The electrochemical oxidative behavior of a series of cyclopentadienyl and pentamethylcyclopentadienyl carbonyl complexes of rhodium and cobalt is described. The voltammetric, polarographic, and coulometric data from the ...
Fast charge-transfer reactions of binuclear complexes undergoing large changes in metal---metal bond lengths
(Elsevier: Journal of Electroanalytical Chemistry, 1987-05-08)
Heterogeneous electron-transfer rates have been measured for three binuclear complexes, Cp2Fe2(CO)2(μ-SMe)2, 1, Cp2Fe2(CO)2(μ-PPh2)2, 2, and Cp2Mo2(μ-SMe)4, 3. Dahl and co-workers had shown previously that the cations of ...
Interconversion of conjugated and nonconjugated polyolefin cobalt complexes in two oxidation states: an electrochemical and NMR study
(The American Chemical Society: Journal of the American Chemical Society, 1986-11-26)
The kinetics of interconversion between the conjugated (1,3) and nonconjugated (1,5) isomers of cyclooctatetraene (cot) complexes of CpCo [Cp = C5H5] 1 and *CpCo [*Cp = C5Me5] 2 have been studied. Dynamic NMR studies were ...
Radicals of C7-polyolefin cobalt complexes: electrochemistry, reaction routes, and structure of a resulting dimer
(The American Chemical Society: Organometallics, 1986-07)
The reduction and oxidation of several cyclopentadienyl (Cp) cobalt complexes with pi-bonded CTpolyolefin ligands have been studied by electrochemical methods. The cycloheptadienyl complex CpCo(n^5-C7H9)+ is reversibly ...
Heterogeneous electron-transfer kinetics for some multiply bonded dirhenium complexes
(Elsevier: Journal of Electroanalytical Chemistry, 1985-12-10)
Standard electrochemical rate constants kexob have been measured for the two sequential one-electron oxidations of triply-bonded dirhenium(II) complexes Re2X4(PR3)4, where X = Cl or Br, and PR3 = a monodentate tertiary ...