Now showing items 1-3 of 3

    • Room-temperature rate constant for the hydroperoxo + hydroperoxo reaction at low pressures 

      Takacs, Gerald; Howard, Carleton (The American Chemical Society: The Journal of Physical Chemistry, 1984-05-10)
      The rate constant, k1, for the self-reaction of HO2, HO2 + HO2 --> H2O2 + O2, was investigated in a discharge-flow system at room temperature and low pressures (1-7 torr) of He carrier gas by laser magnetic resonance ...
    • Rotational spectroscopy of DO2 by FIR LMR and millimeter-wave absorption 

      Sears, Trevor; Takacs, Gerald; Howard, Carleton; Crownover, Richard; Helminger, Paul; De Lucia, Frank (Elsevier: Journal of Molecular Spectroscopy, 1986-07)
      We report the measurement of approximately 50 rotational transitions in the DO2 radical between 230 and 2530 GHz by high-resolution millimeter-wave and far-infrared laser magnetic resonance spectroscopy. The radical was ...
    • Temperature dependence of the reaction hydroperoxo (HO2) + hydroperoxo at low pressures 

      Takacs, Gerald; Howard, Carleton (The American Chemical Society: Journal of Physical Chemistry, 1986-02-13)
      The temperature dependence of the self-reaction of HO2, HO2 + HO2 -> H2O2 + O2 (k1) (1), was investigated by detecting HO2 with laser magnetic resonance in a low-pressure flow tube coated with halocarbon wax. Two independent ...