| dc.contributor.author | Takacs, Gerald | en_US |
| dc.contributor.author | Howard, Carleton | en_US |
| dc.date.accessioned | 2006-07-19T20:07:26Z | en_US |
| dc.date.available | 2006-07-19T20:07:26Z | en_US |
| dc.date.issued | 1986-02-13 | en_US |
| dc.identifier.citation | Journal of Physical Chemistry 90N4 (1986) 687-690 | en_US |
| dc.identifier.issn | 1520-5215 | en_US |
| dc.identifier.uri | http://hdl.handle.net/1850/2259 | en_US |
| dc.description.abstract | The temperature dependence of the self-reaction of HO2, HO2 + HO2 -> H2O2 + O2 (k1) (1), was investigated by detecting HO2 with laser magnetic resonance in a low-pressure flow tube coated with halocarbon wax. Two independent chemical reactions (CH2OH + O2 and F + H2O2) were used to produce HO2 and two calibration procedures were used to determine the concentration of HO2. With 95% confidence limits, k1(T) = (2.0 * 0.6)) X exp[(595 +- 120)/T] cm3 molecule-1 s-1 for the pressure-independent bimolecular channel of reaction 1 from 253 to 390 K, where -d[HO2]/dt = 2k1[HO2]2. | en_US |
| dc.format.extent | 31371 bytes | en_US |
| dc.format.mimetype | application/pdf | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | The American Chemical Society: Journal of Physical Chemistry | en_US |
| dc.title | Temperature dependence of the reaction hydroperoxo (HO2) + hydroperoxo at low pressures | en_US |
| dc.type | Abstract | en_US |
| dc.subject.keyword | Atmospheric H02 | en_US |
| dc.subject.keyword | Self-reactions | en_US |
| dc.subject.keyword | Temperature dependence | en_US |
| dc.identifier.url | http://dx.doi.org/10.1021/j100276a041 | |
